Original Article

Experimental study of magnesium extraction from calcium carbide precipitator dust by silicothermal method

¹ School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, PR China
² College of Materials Science and Engineering, Chongqing University, 174 Shazheng Street, Shapingba District, Chongqing 400044, PR China

^* e-mail: mhzwyn@126.com

Received: 16 July 2024
Accepted: 8 November 2024

Abstract

Calcium carbide precipitator dust is a kind of solid waste containing high calcium oxide and magnesium oxide produced in the process of calcium carbide production. The extraction of magnesium from dust by vacuum silicothermic reduction with ferrosilicon as a reducing agent was studied. The effects of heating temperature, holding time, addition of ferrosilicon and calcium-to-magnesium ratio on the volatilization rate of magnesium in dust were studied. The results indicate that when ferrosilicon is used at an Mg:Si molar ratio of 2:1.05, and calcium oxide to magnesium oxide in the dust at a CaO:MgO molar ratio of 1.2:1, heating the compressed mixture to 1300 °C for 3 h can achieve a magnesium volatilization rate of 91.65%. When the CaO/MgO ratio was less than 1, 2CaO · MgO · 2SiO₂ and 3CaO · MgO · 2SiO₂ containing MgO were formed, resulting in a decrease in the volatilization rate of MgO.